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    超临界水和过热蒸汽作用下的块煤热解试验研究

    Experimental study on pyrolysis of lump coal under the action of supercritical water and superheated steam

    • 摘要: 利用超临界水和过热蒸汽进行煤原位热解,将固体煤转化为可燃气体,是煤流体化开采的重要技术手段。利用新开发研制的高温高压反应釜,开展了块状烟煤的热解试验研究,探索了超临界水及过热蒸汽对煤热解的影响机制,分析超临界水和过热蒸汽温度和压力对煤热解产物及热解速率的影响规律。研究表明:超临界水作用下24Mpa的700℃与400℃相比,产气量提升了约43倍,析出气体中氢气的含量提升了29%,甲烷含量降低了7%,一氧化碳和二氧化碳含量分别降低了10%和12%,失重率提升了20%。700℃下的30Mpa(超临界水)与10Mpa(过热蒸汽)相比,产气量提升了16%,析出气体中氢气的含量提升了14%,甲烷含量基本不变,一氧化碳和二氧化碳含量分别降低了3%和13%,失重率提升了3%。研究结果对煤原位流体化开采工艺参数的确定具有重要的参考价值。

       

      Abstract: Using supercritical water and superheated steam to pyrolyze coal in situ and convert solid coal into combustible gas is an important technical means of coal fluidization mining.In this paper, a newly developed high-temperature and high-pressure reactor was used to carry out a pyrolysis test of lump bituminous coal, and the influence mechanism of supercritical water and superheated steam on coal pyrolysis was explored,Analysis of the influence of supercritical water and superheated steam temperature and pressure on coal pyrolysis products and pyrolysis rate.The study showed that: compared with 400℃, the gas production at 700℃ under 24Mpa increased by about 43 times, the hydrogen content in the precipitated gas increased by 29%, the methane content decreased by 7%, the carbon monoxide and carbon dioxide contents decreased by 10% and 12% respectively, and the weight

       

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