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    基于恒温热重法的准东煤/生物质/废轮胎颗粒点火及燃烧行为研究

    Study on ignition and combustion behavior of Zhundong coal/biomass/waste tire particles based on constant temperature thermogravimetric

    • 摘要: 随着中国电力需求的持续增长,电厂在提升资源利用效率和减少污染物排放方面面临巨大挑战。新疆准东地区虽拥有丰富的煤炭储量,但煤炭燃烧产生的二氧化碳阻碍了“碳达峰”与“碳中和”目标的实现。生物质和废旧轮胎因其可再生性、高热值及低污染排放等特点,成为潜在替代燃料。现有关于点火与燃烧的研究,普遍存在加热速率偏低的问题,难以模拟锅炉内的快速升温条件。为此,采用恒温热重法,利用竖式炉在700、800和900 ℃温度下模拟准东煤、生物质及废轮胎颗粒的点火与燃烧行为,并通过工业CCD相机和电子天平采集数据。通过恒温热重法对颗粒进行加热,并监测其燃烧阶段。重点考察了点火延迟时间( t\mathrm_i )、挥发分和焦炭燃尽时间( t\mathrm_v 和 t_\mathrmc ),通过双色法获得了燃烧火焰中颗粒挥发分和焦炭火焰的最高温度( Tv_\mathrmmax 和 Tc\mathrm_max )。结果表明:生物质颗粒表现为均相点火;准东煤中只有挥发分含量高的大南湖煤(Da Nan Hu Coal,DNH)表现出均相点火。在T=700 ℃时,农业生物质玉米秸秆(Corn Straw, CS)的 Tv\mathrm_max 最高,为1263.8 ℃;在T=800和900 ℃时,木质生物质果木(Fruit Wood,FW)的 Tv_\mathrmmax 最高,分别为1293.31340.8 ℃。而在T=700、800 和900 ℃时,西黑山煤(Xi Hei Shan Coal,XHS)的 Tc\mathrm_max 最高,分别为982.4、1090.41195.85 ℃。此外,研究发现 Tv\mathrm_max 和 t_\mathrmv 与颗粒单位体积内挥发分的含量无直接关系。该研究为准东煤、生物质与废轮胎颗粒的燃烧特性提供了有价值的见解,有助于制定燃料掺混与燃烧优化策略,提升能源利用效率并减少排放,推动可持续能源实践。

       

      Abstract: With the continuous growth in China’s electricity demand, power plants face significant challenges in enhancing resource utilization efficiency and reducing pollutant emissions. Although the Zhundong region of Xinjiang possesses abundant coal reserves, the carbon dioxide produced from coal combustion impedes the achievement of carbon peaking and carbon neutrality goals. Biomass and waste tires have emerged as potential alternative fuels due to their renewability, high calorific value, and low pollutant emissions. However, existing ignition and combustion studies suffer from low heating rates, making it difficult to accurately simulate the rapid temperature rise conditions within boilers. Isothermal thermogravimetric analysis is employed, with a vertical furnace utilized to simulate the ignition and combustion behaviors of Zhundong coal, biomass, and waste tire particles at temperatures of 700, 800, and 900 ℃, while collectingdata using an industrial CCD camera and an electronic balance. The particles were heated using isothermal thermogravimetric analysis, and their combustion stages were monitored. The study examined ignition delay time ( t_\mathrmi ), volatile matter burnout time ( t_\mathrmv ), and char burnout time ( t_\mathrmc ), and utilized the two-color method to obtain the maximum temperatures of volatile matter and char flames ( Tv_\mathrmmax and Tc_\mathrmmax ) within the combustion flame. The results indicate that biomass particles exhibit homogeneous ignition. Among the Zhundong coals, only Da Nan Hu Coal (DNH), which has a high volatile matter content, exhibited homogeneous ignition. At T = 700 ℃, agricultural biomass corn straw (CS) achieved the highest Tv_\mathrmmax of 1263.8 ℃. At T=800 and 900 ℃, woody biomass fruit wood (FW) attained the highest Tv_\mathrmmax , measuring 1293.3 and 1340.8 ℃, respectively. At T=700, 800, and 900 ℃, Xi Hei Shan Coal (XHS) reached the highest Tc_\mathrmmax values of 982.4, 1090.4, and 1195.85 ℃, respectively; Tv_\mathrmmax and tv were not directly related to the volatile matter content per unit volume of the particles. The research provides valuable insights into the combustion characteristics of Zhundong coal, biomass, and waste tire particles, aiding in the development of fuel blending and combustion optimization strategies to enhance energy utilization efficiency and reduce emissions, thereby promoting sustainable energy practices.

       

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