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    有机朗肯循环耦合二氧化碳捕集系统运行仿真与性能评估

    Effect analysis of carbon dioxide capture system with integrated organic Rankine cycle

    • 摘要: 化学吸收法是燃煤电厂二氧化碳捕集的主流高效技术,可显著削减电厂CO2直接排放量,但该技术存在明显能耗短板,CO2高温解吸工序需消耗大量电厂抽汽蒸汽,造成机组供电效率大幅衰减、发电能耗成本上升,严重制约了碳捕集技术在燃煤电厂的规模化工程应用。为有效抵消碳捕集系统的能耗损失,降低其对电厂发电性能的负面影响,提出一种耦合有机朗肯循环的新型碳捕集集成系统,依托ORC低温余热发电特性,回收碳捕集工序中的低品位余热实现能量再生。基于化工流程分析软件Aspen plus建立每年百万吨CO2捕集工艺流程模型,并集成有机朗肯循环回收解吸塔排气和再沸器凝结水余热。选取RC318、R152a、R600a、R600、R245fa共5种有机工质,模拟分析5种工质的流量及其蒸发压力对有机朗肯循环系统的净发电功率、吸热量、热效率与㶲效率以及集成系统的冷却水循环量的影响。结果表明:集成系统中有机工质的蒸发压力和流量均与净发电功率成正比,但蒸发压力和流量具有相互制约的关系;集成系统的ORC加热热源主要来源于解吸塔再生气余热,是余热回收的核心来源;5种工质中R152a综合运行性能最优,其在蒸发压力为3 MPa,流量为188 kg/s时净发电功率最大,可达7.29 MW,同时仅造成2.36%的冷却水循环量增幅,可有效弥补碳捕集能耗损耗,将燃煤电厂发电效率损失降低18.50%。

       

      Abstract: Chemical absorption represents a mainstream and efficient technology for carbon dioxide capture in coal-fired power plants, which can drastically cut direct CO2 emissions of power units. Nevertheless, this technique suffers from prominent energy consumption drawbacks. A large volume of extracted steam from power plants is consumed during the high-temperature CO2 desorption process, leading to sharp declines in power supply efficiency and rising power generation costs. Such issues greatly hinder the large-scale engineering application of carbon capture technology in coal-fired power units. To offset the energy loss of carbon capture systems and mitigate their adverse impacts on power plant performance, this paper proposes a novel integrated carbon capture system coupled with an Organic Rankine Cycle (ORC). Leveraging the low-grade waste heat power generation characteristics of ORC, the system recovers low-temperature waste heat generated in carbon capture processes for energy regeneration.A process model for capturing one million tons of CO2 annually is established using the chemical process simulation software Aspen Plus, with an integrated ORC unit deployed to recover waste heat from stripper overhead gas and reboiler condensate water. Five organic working fluids, namely RC318, R152a, R600a, R600 and R245fa, are selected for simulation. The influences of working fluid mass flow rate and evaporation pressure on the net power output, heat absorption capacity, thermal efficiency, exergy efficiency of the ORC system, as well as the cooling water circulation flow rate of the integrated system are analyzed systematically.Simulation results indicate that both the evaporation pressure and mass flow rate of organic working fluids in the integrated system are positively correlated with net power output, while a mutual restriction exists between these two parameters. The primary heat source for heating the ORC working fluid originates from the waste heat of stripper regenerated gas, which serves as the core source of waste heat recovery. Among the five working fluids, R152a exhibits the optimal comprehensive performance. Under the optimal operating conditions of 3 MPa evaporation pressure and a mass flow rate of 188 kg/s, the maximum net power output reaches 7.29 MW. Meanwhile, it only induces a 2.36% increase in cooling water circulation flow rate. This scheme can effectively compensate for the energy consumption penalty of carbon capture and reduce the power generation efficiency loss of coal-fired power plants by 18.50%.

       

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