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    燃煤掺烧氢对燃烧特性影响的试验研究

    Experimental study on influence of coal/hydrogen co-firing on combustion characteristics

    • 摘要: 氢作为无碳燃料,具有产量大、无污染以及零碳排放等特点。工业锅炉通过燃煤掺氢燃烧可以减少含碳燃料的使用进而有效降低碳排放,但掺烧氢会对NOx排放产生影响。首先对绿氢进行技术经济分析与传统化工燃料进行对比,并在50 kW下行炉燃烧试验炉上开展了燃煤掺氢燃烧试验,研究NOx、CO及CO2生成规律,并在空气分级的基础上,对掺氢比以及燃尽风等影响因素进行了研究。结果表明:目前,风能和太阳能等无法储存的废弃电力制取绿氢会有较好的经济性。试验分析,在一定的燃尽风下,随着掺氢比的增加,CO2的排放量逐渐降低,NOx排放出现先降低后升高的趋势,在30%掺氢比下NOx的排放量最低,为263.3 mg/m3(对应氧气体积分数为3.5%);CO排放量随着掺氢比的增加出现先升高后降低的情况。在一定的掺氢比下,随着燃尽风增加,NOx的排放急剧降低,燃尽风从17%增加到52%,NOx排放量从742.7 mg/m3降低到193.6 mg/m3。此次掺烧研究为燃煤掺氢技术在大型工业锅炉中应用提供了数据支撑,促进了氢燃料在燃煤发电领域的发展,有助于燃煤锅炉“双碳”目标的实现。总体而言,燃煤掺氢技术兼具碳减排潜力和燃烧调控复杂性,未来若能与尾部烟气净化及碳捕集系统协同运行,将在火电行业低碳转型中发挥更为积极的作用。

       

      Abstract: Hydrogen, as a carbon-free fuel, is characteristic of highly productive, non-polluting and zero carbon emissions. Hydrogen combustion in industrial gas boilers can reduce the use of carbon-containing fuels, but it will have an impact on NOx emissions. In this paper, a techno-economic analysis of green hydrogen was carried out. As well as coal/hydrogen co-firing experiments were conducted on a 50 kW downstream furnace. which can achieve self-sustained combustion of pulverized coal. The generation of NOx, CO and CO2, and the impacts of hydrogen co-firing ratio were investigated on the basis of air staged combustion. The findings demonstrate that at present, it is economically feasible to produce hydrogen from waste electricity that cannot be stored, such as wind and solar energy. As the hydrogen co-firing ratio rises, the emission of CO2 gradually decreases, the emission of NOx increases and subsequently decreases. The lowest NOx emission at 30% hydrogen ratio is 263.3 mg/m3, or oxygen volume fraction is 3.5%. The rise in hydrogen doping ratio causes a first increase in CO emissions followed by a reduction. When burnout air rate is increased in a specific hydrogen co-firing ratio, the emission of NOx significantly decreases. Compared to 17% burnout air, there is a significant reduction in NOx emissions at 52% burnout air. With 17% burnout air, the emission of NOx is decreased from 742.7 mg/m3 to 193.6 mg/m3. This research advances the development of hydrogen fuel in the field of coal-fired power generation, supports the use of hydrogen doping technology in large-scale industrial boilers with data, and helps coal-fired boilers achieve their “dual-carbon” goal. Overall, coal co-firing with hydrogen technology possesses both carbon reduction potential and combustion regulation complexity. In the future, if it can be operated synergistically with tail-end flue gas purification and carbon capture systems, it will play a more positive role in the low-carbon transformation of the thermal power industry.

       

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