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    二氧化碳矿化养护全固废轻骨料试验

    Carbon dioxide mineralization maintenance of all-solid waste lightweight aggregates

    • 摘要: 针对传统骨料密度高、强度低的问题,为实现工业固废和捕集后CO2的资源化利用,以高炉渣和粉煤灰为原料,研究了固废配比、剩余水固比、养护压力对轻骨料的筒压强度、固碳率以及堆积密度的影响,从而获得了初步的配方和养护制度,结果表明:粉煤灰从0增加到60%的过程中堆积密度迅速从1 016 kg/m3下降到883 kg/m3,下降了13%,继续增加粉煤灰含量,堆积密度变化不显著,而筒压强度与固碳率均呈现先升高后降低的趋势;通过调整剩余水固比与养护压力,发现存在最佳剩余水固比(0.15)与养护压力(0.1 MPa)使骨料获得最佳的筒压强度;固碳率随着剩余水固比增加而下降,随着养护压力上升而增加。在此基础上研究了氢氧化钠、氢氧化钙、水玻璃3种不同的碱激发剂对轻骨料样品在矿化养护条件下的作用以及影响。结果表明:5%的氢氧化钙对筒压强度性能的提升最优(7.6 MPa),并能显著改善材料的固碳率(5.09%)。通过XRD和SEM分析得出,主要矿化产物为碳酸钙,并以方解石的形态存在,较高的养护压力易导致产物界面出现细微裂缝;通过MIP分析可知,矿化产物对小于100 nm的孔隙有填充作用,由于矿化反应前期放热造成产物的体积膨胀使得大于1 000 nm的孔隙增多,孔隙率的变化表明矿化对微孔结构的巨大改善,解释了矿化提升强度的机理。

       

      Abstract: Aiming at the problem of high density and low strength of traditional aggregates, in order to realize the resource utilization of industrial solid waste and CO2 after capture, using blast furnace slag and fly ash as raw materials, the effects of solid waste proportion, remaining water-solid ratio, and maintenance pressure on the barrel compression strength, carbon sequestration rate, and the stacking density of lightweight aggregates were investigated to obtain the preliminary formulations and maintenance regimes, and the results showed that, the stacking density rapidly decreased from 1 016 kg/m3 to 883 kg/m3 by 13% when increasing fly ash content from 0 to 60%, and both barrel compression strength and carbon sequestration rate showed a first increase and then a decrease of 13%. Density rapidly decreased from 1016 kg/m3 to 883 kg/m3, a decrease of 13%, and continued to increase the fly ash content, the change in bulk density was not significant, while the barrel compression strength and carbon sequestration rate showed a trend of increasing and then decreasing; by adjusting the residual water-solids ratio and the maintenance pressure, it was found that there existed an optimum residual water-solids ratio (0.15) and the maintenance pressure (0.1 MPa) so that the aggregates could obtain the best barrel compression strength; the carbon sequestration rate increased with the residual water-solids ratio and maintenance pressure. strength; the carbon sequestration rate decreased with the increase of residual water-solid ratio and increased with the rise of curing pressure. On this basis, the effects of three different alkali exciters, sodium hydroxide, calcium hydroxide and water glass, on the lightweight aggregate samples under mineralized curing conditions were investigated. The results showed that 5% calcium hydroxide optimally enhanced the barrel compression strength performance (7.6 MPa) and significantly improved the carbon sequestration rate of the material (5.09%). Through XRD and SEM analysis, it was concluded that the main mineralization products were calcium carbonate and existed in the form of calcite, and the higher maintenance pressure was easy to lead to the appearance of fine cracks at the interface of the products; through the MIP analysis, it could be seen that the mineralization products had a filling effect on the pore space of less than 100 nm, and due to the exothermic reaction of the product in the early stage of the mineralization reaction caused by the volume expansion of the product made the increase of pore space of more than 1 000 nm, and the change of porosity shows the great improvement of the microporous structure by mineralization, which explains the mechanism of strength enhancement by mineralization.

       

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