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    燃煤机组深度调峰脱硝性能提升技术分析

    Technical analysis of denitrification performance improvement of coal-fired units under deep peak regulation

    • 摘要: 燃煤机组深度调峰时,长期处于低负荷运行工况,导致烟气温度偏离脱硝装置正常工作区间,出现NOx超标排放问题。对燃煤机组的宽负荷脱硝技术进行了梳理,从催化剂侧、喷氨侧、燃烧侧、烟气侧以及给水侧对SCR(selective catalytic reduction,SCR)低负荷下的脱硝改造方案分析,结果表明高性能宽温脱硝催化剂替代和智能精细化喷氨是实现SCR优化运行的趋势。从烟气循环、喷枪位置以及宽温助燃剂对SNCR(selective non-catalytic reduction,SNCR)进行改造,3种改造方案均有利于提高机组低负荷时的脱硝效率。SCR+SNCR联合脱硝改造在循环流化床锅炉应用后能满足机组在30%~100%负荷下的脱硝要求,煤粉炉采用该技术能提高脱硝效率,降低投资成本。臭氧联合SNCR与SCR脱硝可以进一步提高脱硝效率,增强脱硝系统对负荷的适应性。

       

      Abstract: When coal-fired units participate in the deep peak regulation, the units are in low-load operating conditions for a long time, resulting in flue gas temperatures deviating from the normal operating range of denitrification device and excessive NOx emissions. In this paper, the wide load denitrification technologies are sorted out. The selective catalytic reduction (SCR) denitrification transformation schemes are analyzed from the catalyst side, ammonia spraying side, combustion side, flue gas side, and feed water side. The replacement of high-performance wide-temperature denitration catalyst and intelligent fine ammonia injection are the trends to realize the optimal operation of SCR. The selective non-catalytic reduction (SNCR) transformation schemes are analyzed in terms of flue gas circulation, adjustment of spray gun position and addition of wide temperature additive, and the three transformation schemes are conducive to improving the denitrification performance under low load. Combined denitrification technology can improve unit flexibility. Among them, the combined SNCR and SCR denitrification technology of the circulating fluidized bed boiler can meet the denitrification requirements of the unit under 30%−100% load. The combined denitrification technology of the pulverized coal furnace can improve the denitrification efficiency and reduce the investment cost. Ozone combined SNCR and SCR denitrification technology can further improve the denitrification efficiency and improve the adaptability of the denitrification system.

       

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