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    煤焦油、生物质油与重油共减黏裂化的可行性研究

    Feasibility study of co-vis breaking to coal tar or biomass-oil and heavy oil

    • 摘要: 为获得经济的燃料油,论述了重油减黏裂化工艺现状及煤焦油与生物质油加工处理工艺现状,分析了煤焦油、生物质油和重油的减黏裂化机理,研究了煤焦油、生物质油与重油的共减黏裂化工艺的技术可行性。结果表明,减黏裂化工艺主要处理来自石油的重油,煤焦油和生物质油则主要靠加氢裂化来进行轻化和精制处理。煤焦油和生物质油中有机含氧化合物和氧含量明显高于来自石油的重油。煤焦油、生物质油与重油共减黏裂化可实现反应互补,利用煤焦油、生物质油中有机含氧化合物的有机含氧官能团裂解产生的氢质子和游离基碎片,可有效防止重油在减黏裂化时发生聚合反应,减轻结焦,降低燃料液体产物黏度。煤焦油、生物质油与重油的共减黏裂化不仅可提升煤焦油、生物质油和重油的品位,获得更多的轻质油品馏分,还能降低煤焦油、生物质油和重油的综合加工处理成本。

       

      Abstract: In order to obtain lower- priced fuel oil,the feasibility of process for co- vis breaking to coal tar or biomass- oil and heavy oil was explored. The vis- breaking technology was mainly used for processing heavy oil from fossil oil,coal tar and biomass- oil mainly depended on the hydro- cracking of light and refined processing. By studying the mechanism of vis breaking to coal tar or biomass- oil and heavy oil,it was concluded that their reaction on vis- breaking had complementary advantages if they were subjected to co- vis breaking.More organic oxygen functional group were presented in coal tar or biomass- oil,they could become hydrogen donors and / or small free radical fragments generators with small molecular weight during vis breaking,the hydrogen donors and / or small free radical fragments were benefit to vs breaking to coal tar or biomass- oil and vis breaking to heavy oil. The co- vis breaking of coal tar or biomass- oil and heavy oil could improve the quality of coal tar,biomass oil and heavy oil,and get more light oil fraction,it also could greatly reduce the comprehensive processing treatment cost of coal tar or biomass- oil and heavy oil.

       

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