高级检索

    大尺度褐煤煤焦气化特性研究

    Gasification characteristics of large size lignite-char

    • 摘要: 煤层气化是将地下煤层进行有控制的燃烧来获取清洁燃气的技术。本文针对煤层气化过程的特点,利用自行设计的气化实验平台,研究气化剂流量、温度、原煤粒径对大尺度煤焦-水蒸气气化反应碳转化率和反应速率的影响。结果表明:在一定范围内,随水蒸气流量的增加,同一反应时间内煤焦碳转化率增加,气化反应速率也增大。原煤粒径对其气化反应性的影响显著,但无明显变化规律。随着气化温度的升高,煤焦固定碳达到相同碳转化率所需时间逐渐缩短。反应速率常数k随温度升高逐渐变大,反应级数随温度升高降低。实验结果为煤层气化现场实验工艺条件的优化提供了理论参考。

       

      Abstract: Underground coal gasification(UCG) technology can achieve clean gas through controlling the combustion of coal seam underground.Based on the characteristics of coal seam gasification,char-steam reactions at elevated temperature are investigated kinetically using self-designed UCG-simulated gasifier.The effects of temperature,flow rate of steam and particle size of coal on gasification reaction are researched with relevant kinetic parameters.The results show that,in a certain range,with the increase of steam flow rate,the carbon conversion rate and gasification rate increase.The particle size of coal has a significant effect on gasification process,while no obvious change law is observed.The higher the gasification temperature,the shorter the time needed to reach the same carbon conversion rate.The constant of reaction rate k gradually increases with the rise of temperature,but reaction order shows the contrary trend.The results supply a theoretical reference to the optimization of process conditions in UCG.

       

    /

    返回文章
    返回