高级检索

    SNCR/烟气再循环协同脱硝技术研究

    Research on SNCR/flue gas recycling synergistic denitration technology

    • 摘要: 短期内煤炭作为我国主要能源的现状不会改变。由于煤燃烧会释放大量NO_x,造成严重的环境污染,因此煤炭燃烧过程中的NO_x控制至关重要。链条锅炉作为我国工业应用最为广泛的燃煤锅炉之一,是降低NO_x排放的重点对象,尤其在新实施的GB 13271—2014《锅炉大气污染物排放标准》中规定重点地区锅炉NO_x排放值不得高于200 mg/m~3后,链条炉低氮燃烧和NO_x脱除技术受到广泛关注。为降低链条锅炉NO_x排放,满足国家环保要求的同时,降低企业运行维护成本,提高企业经济效益,以西安高新区某供热站4×75 t/h链条锅炉为研究对象,进行烟气再循环与SNCR耦合低氮燃烧NO_x脱除技术改造研究。研究了SNCR与烟气再循环耦合低氮燃烧系统参数,如烟气再循环率,再循环烟气一、二次风室送入比例,氨氮摩尔比,锅炉负荷变化等脱硝系统参数对NO_x脱除效率及链条炉燃烧特性的影响,确定了烟气再循环与SNCR技术耦合脱硝的最佳运行参数,结果表明:SNCR耦合烟气再循环低氮燃烧技术能有效降低链条锅炉NO_x排放。烟气再循环率为16%~18%,再循环烟气一次风室送入比例为82%,氨氮摩尔比为0.78时,SNCR耦合烟气在循环脱硝系统可达最佳脱硝效率。此时SNCR耦合烟气再循环联合脱硝效率可达到56%,SNCR单独运行脱硝效率可达40%,NO_x实际排放可从250 mg/m~3降至110 mg/m~3,远高于国家NO_x排放标准。

       

      Abstract: In the short term,the status quo of coal as the main energy in China will not change.Because coal combustion will release a lot of NO_xand cause serious environmental pollution,so the control of NO_xin coal combustion process is very important.Chain grate furnace as one of the most widely used coal-fired boilers in China must be paid more attention to the reduction of NO_xemission.Especially with the implementation of Boiler Air Pollutant Emission Standard(GB 13271—2014),the NO_xemission value of grate furnace in key areas should not be higher than 200 mg/m~3,the technology of low-nitrogen combustion and NO_xremoval in chain grate furnace has attracted wide attention.In order to reduce the NO_xemission of chain grate furnace,meet the requirements of national environmental protection,reduce the cost of operation and maintenance of enterprises and improve the economic benefits of enterprises,the technical improvement study of flue gas recirculation and SNCR denitrification system was performed in a 4×75 t/h chain grate furnace of a heating station at Gaoxin District in Xi'an to reduce the NO_xemission.The influence of the parameters of SNCR and flue gas recirculation coupled low nitrogen combustion system,such as flue gas recirculation ratio,the feed ratio of recirculation flue gas in primary and second air chamber,the ammonia nitrogen molar ratio and the change of boiler load on NO_xremoval efficiency and combustion characteristics were researched.The optimum operating parameters of flue gas recirculation coupled with SNCR technology were determined.The results show that the SNCR coupled flue gas recirculation low nitrogen combustion technology can effectively reduce the NO_xemission of chain grate furnace.When the flue gas recirculation rate is 16%-18%,the feed ratio of recirculation flue gas in primary air chamber is 82%,and the molar ratio of ammonia nitrogen is 0.78,the SNCR coupled flue gas can achieve the best denitrification efficiency in the circulating system.At this point,the denitration efficiency of SNCR coupling flue gas recycling is up to 56%and the denitrification efficiency of SNCR single operation is 40%and the actual NO_xemission is reduced from 250 mg/m~3to 110 mg/m~3,which is much higher than the national emission standard of NO_x.

       

    /

    返回文章
    返回