煤气化灰渣脱碳技术研究进展Research progress of the decarburization technology of coal gasification ash slag
史达;张建波;杨晨年;曲江山;李少鹏;李会泉;何发钰;
SHI Da;ZHANG Jianbo;YANG Chennian;QU Jiangshan;LI Shaopeng;LI Huiquan;HE Fayu;School of Resources and Civil Engineering,Northeastern University;Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Science;National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology;University of Chinese Academy of Science;China Minmetals Corporation;
摘要(Abstract):
煤气化技术是我国现代煤化工的基础,该过程将煤中有机物转化为化学品,无机物以气化灰渣形式外排。目前煤气化灰渣主要以堆存为主,造成严重的环境和水体污染。在对煤气化灰渣进行消纳处理过程中,因内部含有大量的未燃碳,使其在建工建材等规模化利用途径受限。当前的国内外碳、灰分选方法虽有一定的效果,但基本处于实验室研究和半工业试验阶段,因存在成本高、分选效率低等问题,未能实现大规模工业化应用。碳灰分选效果受煤气化灰渣的矿相组成、物相成分、粒度分布、微观形貌等因素影响,不同类型气化渣需要采取不同的分选工艺,进而实现碳灰的高效分离。结合煤气化灰渣脱碳的主要影响因素,分析了煤气化灰渣脱碳的主要工艺技术和装备,多角度阐述了煤气化灰渣碳、灰组分的主要分离方法,并进一步总结对比各分选方法的工艺特点和不足。分析了各技术在煤气化灰渣脱碳分选应用的发展趋势,指明了研发绿色、高效、低成本的新型浮选药剂,解决煤气化灰渣灰分吸附罩盖问题,开发针对细粒级煤气化灰渣脱碳的分选工艺与装备,实现脱碳分选产品的高值化利用,是当前煤气化灰渣脱碳技术的重要发展方向。
Coal gasification technology is the foundation of modern coal chemical industry in China.In this process,the organic matter in coal is converted into chemicals,and the inorganic matter is discharged in the form of gasification slag.At present,coal gasification slag is mainly stored in piles,causing serious environmental and water pollution.In the process of dissipating coal gasification slag,because of the large amount of unburned carbon inside,the large-scale utilization channels such as construction materials and building materials are limited.Although the current carbon and ash separation methods at home and abroad have certain effects,they are basically in the stage of laboratory research and semi-industrial testing.Due to the problems of high cost and low separation efficiency,large-scale industrial applications have not been realized.The separation of carbon ash is affected by the mineral phase composition,phase composition,particle size distribution,micro-morphology and other factors of coal gasification slag.Different types of gasification slag need to adopt different separation processes to achieve efficient separation of carbon and ash.Combined with the main influencing factors of coal gasification slag decarburization,the main technology and equipment of coal gasification slag decarbonization were analyzed,the main separation methods of carbon and ash components of coal gasification slag were expounded from multiple angles,and the technological characteristics and shortcomings of each sorting method were further Summarized and compared.Finally,the development trend of various technologies in the decarbonization and separation of coal gasification slag was analyzed,and the development of new green,efficient,and low-cost flotation reagents was pointed out to solve the problem of unburned carbon-ash adsorption cover.The separation technology and equipment for the decarbonization of granular coal gasification slag and the realization of high-value utilization of decarbonization separation products is an important development direction of current coal gasification slag decarbonization technology.
关键词(KeyWords):
煤气化灰渣;脱碳;浮选;分离;资源化利用
coal gasification slag;decarbonization;flotation;separation;resource utilization
基金项目(Foundation): 国家重点研发计划资助项目(2019YFC1904302);; 国家自然科学基金资助项目(51804293,U1810205);; 固废资源化利用与节能建材国家重点实验室开放基金资助项目(SWR-2019-005);; 中石化合作企业横向资助项目(419035-3)
作者(Author):
史达;张建波;杨晨年;曲江山;李少鹏;李会泉;何发钰;
SHI Da;ZHANG Jianbo;YANG Chennian;QU Jiangshan;LI Shaopeng;LI Huiquan;HE Fayu;School of Resources and Civil Engineering,Northeastern University;Key Laboratory of Green Process and Engineering,Institute of Process Engineering,Chinese Academy of Science;National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology;University of Chinese Academy of Science;China Minmetals Corporation;
Email:
DOI: 10.13226/j.issn.1006-6772.EP20082501
参考文献(References):
- [1]王迪.中国煤炭产能综合评价与调控政策研究[D].徐州:中国矿业大学,2013:25-30.WANG Di.Study on integrated assessment and regulation policies of China's coal production cpacity[J].Xuzhou:China University of Mining&Technology,2013:25-30.
- [2]丛威.我国煤炭产能调控动力机制及模式研究[D].北京:中国矿业大学(北京),2013:30-36.CONG Wei.Study of dynamic mechanism and mode for China's coal production capacity regulation policy[D].Beijing:China University of Mining&Technology-Beijing,2013:30-36.
- [3]郑欢.中国煤炭产量峰值与煤炭资源可持续利用问题研究[D].成都:西南财经大学,2014:76-94.ZHENG Huan.Research on Chinese coal production peak and sustainable utilization of coal resources[D].Chengdu:Southwestern University of Finance and Economics,2014:76-94.
- [4]傅丛,白向飞,丁华,等.我国动力用煤及煤化工领域对煤质的基本要求[J].煤质技术,2019,34(5):1-8.FU Cong,BAI Xiangfei,DING Hua,et al.Basic requirements of coal quality for Chinese power coal chemical industry[J].Coal Quality Technology,2019,34(5):1-8.
- [5]杨芊,杨帅,樊金璐,等.“十四五”时期现代煤化工煤炭消费总量控制研究[J].煤炭经济研究,2020,40(2):25-30.YANG Qian,YANG Shuai,FAN Jinlu,et al.Research on total coal consumption control of modern coal chemical industry in the"Fourteenth Five-Year Plan"period[J].Coal Economic Research,2020,40(2):25-30.
- [6]徐振刚.中国现代煤化工近25年发展回顾·反思·展望[J].煤炭科学技术,2020,48(8):1-25.XU Zhengang.Review,rethink and prospect of China's modern coal chemical industry development in recent 25 years[J].Coal Science and Technology,2020,48(8):1-25.
- [7]沙兴中,杨南星.煤的气化与应用[M].上海:华东理工大学出版社,1995:14-17.SHA Xingzhong,YANG Nanxing.Gasification and application of coal[M].Shanghai:East China University of Science and Technology Press,1995:14-17.
- [8]卢珊珊.气流床煤气化灰渣的特性研究[D].上海:华东理工大学,2011:3-5.LU Shanshan.Study on the characteristics of slag and fly ash which generated from entrained-bed gasifiers[D].Shanghai:East China University of Science and Technology,2011:3-5.
- [9]许慎启.煤气化反应动力学及渣中残碳反应活性研究[D].上海:华东理工大学,2011:1-7.XU Shenqi.Gasification kinetics study of coal char and unburned carbon in slag[D].Shanghai:East China University of Science and Technology,2011:1-7.
- [10]张晓峰,王玉飞,范晓勇,等.煤气化细渣浮选脱碳分析[J].能源化工,2016,37(5):54-57.ZHANG Xiaofeng,WANG Yufei,FAN Xiaoyong,et al.Analysis on decarbonization of coal gasification fine slag flotation[J].Energy and Chemical Industry,2016,37(5):54-57.
- [11]WANG S.Development and application of modern coal gasification technology[J].Chemical Industry and Engineering Progress,2016,35(3):653-664.
- [12]董永波.水煤浆气化细渣碳资源回收及循环利用[J].氮肥技术,2018,39(3):25-36.DONG Yongbo.Recovery and recycling of fine slag carbon resources from coal water slurry gasification[J].Nitrogen fertilizer technology,2018,39(3):25-36.
- [13]RATAFIA-BROWN J A,MANFREDO L M,HOFFMANN J W,et al.In an environmental assessment of IGCC power systems[C]//Nineteenth Pittsburgh Coal Conference.Pittsburgh,2002:16-17.
- [14]ZOU Caineng,CHEN Yanpeng,KONG Lingfeng,et al.Underground coal gasification and its strategic significance to the development of natural gas industry in China[J].Petroleum Exploration and Development,2019,46(2):205-215.
- [15]曲江山,张建波,孙志刚,等.煤气化渣综合利用研究进展[J]洁净煤技术,2020,26(1):184-192.QU Jiangshan,ZHANG Jianbo,SUN Zhigang,et al.Research progress on comprehensive utilization of coal gasification slag[J].Clean Coal Technology,2020,26(1):184-192.
- [16]胡文豪.煤气化渣铝硅组分活化分离与资源化利用基础研究[D].北京:中国科学院大学,2019.HU Wenhao.Basic study on activation separation and resource utilization of Al-Si components in coal gasification residue[D].Beijing:University of Chinese Academy of Sciences,2019.
- [17]LI Zuzhong,ZHANG Yayun,ZHAO Hongyan,et al.Structure characteristics and composition of hydration products of coal gasification slag mixed cement and lime[J].Construction and Building Materials,2019,213:265-274.
- [18]WU T,GONG M,LESTER E,et al.Characterisation of residual carbon from entrained-bed coal water slurry gasifiers[J].Fuel,2007,86:972-982.
- [19]WU S,HUANG S,JI L,et al.Structure characteristics and gasification activity of residual carbon from entrained-flow coal gasification slag[J].Fuel,2014,122:67-75.
- [20]ACOSTA A,IGLESIASA I,AINETOA M,et al.Utilisation of IGCCslag and clay steriles in soft mud bricks(by pressing) for use in building bricks manufacturing[J].Waste Management,2002,22(8):887-891.
- [21]LI Zuzhong,ZHANG Yayun,ZHAO Hongyan,et al.Structure characteristics and composition of hydration products of coal gasification slag mixed cement and lime[J].Construction and Building Materials,2019,213:265-274.
- [22]YOSHITAKA I.Utilization of coal gasification slag collected from IGCC as fine aggregate for concrete[C]//Proceedings of the EU-ROCOALASH 2012 Conference.Greece,2012:1-8.
- [23]MARTIN I,ECHEVERIA A A,GARCIA-ROMERO E.Recycling of residual IGCC slags and their benefits as degreasers in ceramics[J].Journal of Environment Management,2013,129:1-8.
- [24]WU S,HUANG S,WU Y,et al.Characteristics and catalytic actions of inorganic constituents from entrained-flow coal gasification slag[J].Energy Insitute,2015,88(1):93-103.
- [25]DUAN W,YU Q,LIU J,et al.Characterizations of the hot blast furnace slag on coal gasification reaction[J].Applied Thermal Engineering,2016,98:936-943.
- [26]MATJIE R H,LI Z,WARD C R,et al.Chemical composition of glass and crystalline phases in coarse coal gasification ash[J].Fuel,2008,87(6):857-869.
- [27]JENNER H A,JANSSEN-MOMMEN J P M,KOEMAN J H.Effects of coal gasification slag as a substrate for the plant cyperus esculentus and the worm Eisenia fetida[J].Ecotoxicol.Environ.Saf.,1992,24(1):45-67.
- [28]YUAN H,YIN H,TANG Y,et al.The basic characteristics of gasification slag from texaco gasifier and shell gasifier[J].Applied Mechanics and Materials,2014,675:728-732.
- [29]赵永彬,吴辉,蔡晓亮,等.煤气化残渣的基本特性研究[J].洁净煤技术,2015,21(3):110-113,74.ZHAO Yongbin,WU Hui,CAI Xiaoliang,et al.Research on the basic characteristics of coal gasification residue[J].Clean Coal Technology,2015,21(3):110-113,74.
- [30]高旭霞,郭晓镭,龚欣,等.气流床煤气化渣的特征[J].华东理工大学学报(自然科学版),2009,35(5):677-683.GAO Xuxia,GUO Xiaolei,GONG Xin,et al.Characteristics of coal gasification slag in airstream bed[J].Journal of East China University of Science and Technology(Natural Science edition),2009,35(5):677-683.
- [31]盛羽静.气流床气化灰渣的理化特性研究[D].上海:华东理工大学,2017:28-45.SHENG Yujing.Study on physicochemical characteristics of slag from entrained-flow goal gasification[D].Shanghai:East China University of Science and Technology,2017:28-45.
- [32]PAN Chanchan,LIANG Qinfeng,GUO Xiaolei,et al.Characteristics of different sized slag particles from entrained-flow coal gasification[J].Energy Fuels,2016,30(2):1487-1495.
- [33]GUO Fanhui,MIAO Zekai,GUO Zhenkun,et al.Properties of flotation residual carbon from gasification fine slag[J].Fuel,2020,267:1-8.
- [34]AI Weidong,ZHANG Jiupeng,MIAO Shiding,et al.A low-cost and high-value reinforcing filler for styrene butadienerubber fabricated by a pneumatic separation technique from coal gasification fine slag[J].Polymer Journal,2019,15:1-11.
- [35]张晓峰,王玉飞,党睿,等.煤气化细渣特性对其浮选脱碳过程的影响[J].河南化工,2016,33(7):11-13.ZHANG Xiaofeng,WANG Yufei,DANG Rui,et al..Influence of fine slag characteristics of coal gasification on its flotation decarburization process[J].Henan Chemical Industry,2016,33 (7):11-13.
- [36]马飞,李寒旭,盛新,等.Shell煤气化飞灰粘附特性及沉积机理分析[J].煤炭科学技术,2010,38(10):114-117.MA Fei,LI Hanxu,SHENG Xin,et al.Adhesion characteristics and deposition mechanism of Shell gasification fly ash[J].Coal Science and Technology,2010,38(10):114-117.
- [37]ZHAO Xianglong,ZENG Cai,MAO Yanyan,et al,The surface characteristics and reactivity of residual carbon in coal gasification slag[J].Energy and Fuels,2010,24:91-94.
- [38]王淀佐,胡跃华.浮选溶液化学[M].长沙:湖南科学技术出版社,1988:10-35.WANG Dianzuo,HU Yuehua.Solution chemistry of flotation[M].Changsha:Hunan Science&Technology Press,1988:10-35.
- [39]ZHANG Rui,GUO Fangyu,XIA Yangchao,et al,Recovering unburned carbon from gasification fly ash using saline water[J].Waste Management,2019,98:29-36.
- [40]邹涛,林益安,刘军,等.基于气化黑水的含油废弃物热洗-细渣高值利用集成工艺:CN110422975A[P].2019-11-08.ZOU Tao,LIN Yian,LIU Jun,et al.Integrated Process of oilbearing waste thermal washing and fine slag high-value utilization based on gasification black water:CN110422975A[P].2019-11-08.
- [41]ZHOU Feng,YAN Chunjie,WANG Hongquan,et al.The result of surfactants on froth flotation of unburned carbon from coal fly ash[J].Fuel,2017,190:182-188.
- [42]胡俊阳.北方某煤气化炉渣的综合利用研究[D].绵阳:西南科技大学,2018.HU Junyang.Study on the comprehensive utilization of a coal gasification slag in the North[D].Mianyang:Southwest University of Science and Technology,2018.
- [43]白雪杰,朱金波.煤泥浮选设备研究现状及进展[J].煤炭加工与综合利用,2017(1):40-42,46.BAI Xuejie,ZHU Jinbo.Research Status and development of slime flotation equipment[J].Coal Processing&Comprehensive Utilization,2017(1):40-42,46.
- [44]UURUM M.Influences of Jameson flotation operation variables on the kinetics and recovery of unburned carbon[J].Power Technology,2009,191(3):240-246.
- [45]李春启,杨明顺,康善娇,等.煤气化细渣分选及回用的方法:CN105524669A[P].2016-04-27.LI Chunqi,YANG Mingshun,KANG Shanjiao,et al.Separation and reuse of coal gasification fine slag:CN105524669A[P].2016-04-27.
- [46]张一昕,郭凡辉,武建军,等.一种煤气化细渣浮选分离脱水系统及方法:CN110052334A[P].2019-07-26.ZHANG Yixin,GUO Fanhui,WU Jianjun,et al.The invention relates to a coal gasification fine slag flotation separation dewatering system and a method:CN110052334A[P].2019-07-26.
- [47]葛晓东.煤气化细渣表面性质分析及浮选提质研究[J].中国煤炭,2019,45(1):107-112.GE Xiaodong.Study on surface properties of coal gasification fine slag and its flotation[J].China Coal,2019,45(1):107-112.
- [48]吴阳.煤气化灰渣的分选加工利用研究[D].西安:西安科技大学,2017:42-53.WU Yang.Study on separation,processing and utilization of coal gasification ash residue[J].Xi'an:Xi'an University of Science and Technology,2017:42-53.
- [49]赵世永,吴阳,李博.Texaco气化炉灰渣理化特性与脱碳研究[J].煤炭工程,2016,48(9):29-32.ZHAO Shiyong,WU Yang,Li Bo.Physicochemical properties and decarbonization of ash residue in Texaco gasifier[J].Coal Engineering,2016,48(9):29-32.
- [50]XU M,ZHANG H,LIU C.A comparison of removal of unburned carbon from coal fly ash using a traditional flotation cell and a new flotation column[J].Physicochemical Problems of Mineral Processing,2017,53(1):628-638.
- [51]谢广元,张明旭,边炳鑫,等.选矿学[M].徐州:中国矿业大学出版社,2002:99-102.XIE Guangyuan,ZHANG Mingxu,BIAN Bingxin,et al.Beneficiation science[M].Xuzhou:China University of Mining&Technology,2002:99-102.
- [52]National Energy Technology Laboratory.Gasifier by-product handling experience[EB/OL].(2020-03-26)[2020-03-26].https://www.netl.doe.gov/research/Coal/energysystems/gasification/gasifipedia/byproduct-handling.
- [53]CHARLES E Price,MADISONVILLE K Y.Method and system for beneficiating gasification slag:US 7328805B2[P].2008-02-12.
- [54]杨玉芬,陈清如,骆振福.流态化技术干法脱炭的理论分析与试验研究[J].中国矿业大学学报,2003,32(6):36-39.YANG Yufen,CHEN Qingru,LUO Zhenfu.Theoretical analysis and experimental study of fluidization dry process for carbon removal[J].Journal of China University of Mining&Technology,2003,32(6):36-39.
- [55]杨玉芬,陈清如,黎强.空气重介质流化床分选技术分析[J].淮南工业学院学报,2002(1):36-39.YANG Yufen,CHEN Qingru,LI Qiang.Analysis of air heavy medium fluidized bed separation technology[J].Journal of Huainan Institute of Technology,2002(1):36-39.
- [56]章新喜,章明玥,段超红,等.气化炉灰渣中碳的回收方法:CN101870896A[P].2010-10-27.ZHANG Xinxi,ZHANG Mingyue,DUAN Chaohong,et al.Recovery method of carbon from gasification furnace ash and slag:CN101870896A[P].2010-10-27.
- [57]赵鹏,邵伟,陈剑宁,等.一种德士古炉水煤浆气化废渣的综合利用方法:CN101456689A[P].2009-06-17.ZHAO Peng,SHAO Wei,CHEN Jianning,et al.A comprehensive utilization method of Texaco coal water slurry gasification waste slag:CN101456689A[P].2009-06-17.
- [58]纪龙,曾鸣.燃煤电厂CO2捕集与利用技术综述[J].煤炭工程,2014,46(3):90-92.JI Long,ZENG Ming.A review of CO2capture and utilization in coal-fired power plants[J].Coal Engineering,2014,46(3):90-92.
- [59]张东明,杨晨,周海滨.二氧化碳捕集技术的最新研究进展[J].环境保护科学,2010,36(5):7-9,35.ZHANG Dongming,YANG Chen,ZHOU Haibin.Recent advances in carbon dioxide capture technology[J].Environmental Protection Science,2010,36(5):7-9,35.
- [60]骆仲泱,方梦祥,李明远,等.二氧化碳捕集封存和利用技术[M].北京:中国电力出版社,2012:166-167.LUO Zhongyang,FANG Mengxiang,LI Mingyuan,et al.Carbon dioxide capture,storage and utilization technology[M]].Beijing:China Electric Power Press,2012:166-167.
- [61]李现勇.整体煤气化联合循环(IGCC)发电和二氧化碳减排技术[C]//2009年二氧化碳减排控制技术与资源化利用研讨会论文集.上海:上海人民出版社,2010:59-64.LI Xianyong.Integrated gasification combined cycle and CO2reduction technologies[C]//Proceedings of the 2009 Symposium on Carbon Dioxide Emission Reduction and Control Technologies and Resource utilization.Shanghai:Shanghai People's Publishing House,2010:59-64.
- [62]张启阳,黄凤敏,陆诗建,等.燃烧前脱碳技术与工程进展[J].应用化工,2015,44(7):1331-1334.ZHANG Qiyang,HUANG Fengmin,LU Shijian,et al.Advances in decarbonization technology and Engineering before combustion[J].Applied Chemical Industry,2015,44(7):1331-1334.
- [63]梅琳,卢啸风,王泉海,等.飞灰流化床燃烧脱碳的试验研究[J].中国电机工程学报,2014,34(26):4454-4461.MEI Lin,LU Xiaofeng,WANG Haiquan,et al.Experimental study on decarburization of fly ash in fluidized bed combustion[J].Proceedings of the CSEE,2014,34(26):4454-4461.
- [64]李登新,吕俊复,刘青,等.高碳团聚飞灰的燃烧特性[J].中国电机工程学报,2004,26(11):215-218.LI Dengxin,LYU Junfu,LIU Qing,et al.Combustion characteristics of high carbon agglomerated fly ash[J].Proceedings of the CSEE,2004,26(11):215-218.
- [65]何宏舟.飞灰回燃对燃烧福建无烟煤CFB锅炉运行影响的研究[J].热能动力工程,2006,21(1):53-57,107.He Hongzhou.Study on the effect of fly ash backcombustion on CFB boiler operation of Fujian anythracite[J].Thermal Power Engineering,2006,21(1):53-57,107.
- [66]王金福,唐强,郑妍妍,等.一种煤气化灰渣氧化脱碳制灰分联产蒸汽的方法:CN105441131B[P].2018-04-20.WANG Jinfu,TANG Qiang,ZHENG Yanyan,et al.A method of producing ash and steam by oxidative decarbonization of coal gasification ash:CN105441131B[P].2018-04-20.
- [67]MCMAHAN L Gray,KENNETH J Champagne,YEESOONG,et al.Physical cleaning of high carbon fly ash,fuel processing technology[J].Fuel Processing Technology,2002,76(1):11-21.
- [68]王启民.循环流化床锅炉飞灰高压静电脱碳的研究[D].北京:清华大学,2006:10-37.WANG Qimin.A study on CFB boiler fly ash triboelectrostatic separation[D].Beijing:Tsinghua University,2006:10-37.
- [69]张全国,李刚,徐波,等.粉煤灰静电脱炭技术研究[J].安全与环境学报,2002,2(1):47-50.Zhang Quanguo,Li Gang,Tao Youjun,et al.Simulation study of fly ash particle motion characteristics in rotary tribological elector[J].Journal of China University of Mining&Technology,2002,2(1):47-50.
- [70]张全国,杨群发,焦有宙,等.粉煤灰高压静电脱炭工艺特性的试验研究[J].粉煤灰,2002(5):3-6.ZHANG Quanguo,YANG Qunfa,JIAO Youzhou,et al.Experimental study on the characteristics of high pressure electrostatic decarbonization process for fly ash[J].Fly Ash,2002(5):3-6.
- [71]张相锋.粉煤灰脱炭试验装置研究[D].郑州:河南农业大学,2000:20-25.ZHANG Xiangfeng.Study of the experimental installation of separating charcoal from fly ash[D].Henan:Henan Agricultural University,2000:20-25.
- [72]SOONG Y,SCHOFFSTALL M R,GRAY M L,et al.Dry beneficiation of high loss-on-ignition fly ash,separation and purification technology[J].Separation and Purification Technology,2002,26(2):177-184.
- [73]JIANG Kelvin,TAO D,STENCEL J M.Enhancement of dry triboelectric separation of fly ash using seed particles[J].Coal Preparation,2003,23(1/2):67-76.
- [74]叶世旺,陶东平,陶有俊,等.旋转摩擦电选起电器内粉煤灰颗粒运动特性的模拟研究[J].中国矿业大学学报,2019,48(6):1343-1351.YE Shiwang,TAO Dongping,TAO Youjun,et al.Simulation study of fly ash particle motion characteristics in rotary tribological elector[J].Journal of China University of Mining&Technology,2019,48(6):1343-1351.
文章评论(Comment):
|
||||||||||||||||||
|
- 史达
- 张建波
- 杨晨年
- 曲江山
- 李少鹏
- 李会泉
- 何发钰
SHI Da- ZHANG Jianbo
- YANG Chennian
- QU Jiangshan
- LI Shaopeng
- LI Huiquan
- HE Fayu
- School of Resources and Civil Engineering
- Northeastern University
- Key Laboratory of Green Process and Engineering
- Institute of Process Engineering
- Chinese Academy of Science
- National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology
- University of Chinese Academy of Science
- China Minmetals Corporation
- 史达
- 张建波
- 杨晨年
- 曲江山
- 李少鹏
- 李会泉
- 何发钰
SHI Da- ZHANG Jianbo
- YANG Chennian
- QU Jiangshan
- LI Shaopeng
- LI Huiquan
- HE Fayu
- School of Resources and Civil Engineering
- Northeastern University
- Key Laboratory of Green Process and Engineering
- Institute of Process Engineering
- Chinese Academy of Science
- National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology
- University of Chinese Academy of Science
- China Minmetals Corporation