邓云鹏;柳明月;袁小华;刘淑琴;
DENG Yunpeng;LIU Mingyue;YUAN Xiaohua;LIU Shuqin;School of Chemical and Environmental Engineering,China University of Mining and Technology (Beijing);

• 1:中国矿业大学(北京)化学与环境工程学院

摘要(Abstract)：

煤气化作为煤化工的龙头技术在推动煤化工可持续发展中具有重要作用,而灰渣的矿物学特征是反映煤气化工况,影响煤气化过程稳定运行的关键因素。阐述了传统气化灰渣矿物成分组成和结构形貌分析表征方法的工作原理和研究现状。分析了一些新发展表征技术在灰渣矿物表征分析中的应用,如高温X射线衍射可直接获得不同温度下矿物质的衍射图谱;穆斯堡尔谱不仅可对煤和灰渣中含铁矿物质进行定性、定量分析,还可确定矿物质中Fe2+/Fe3+、晶体结构参数、固溶体种类和含量;微区分析利用SEM与X射线能谱联用确定矿物的微区成分。在气化灰渣矿物特性分析中,应根据灰渣矿物的组成特点选择适当的表征分析技术。
Coal gasification plays an irreplaceable role in promoting the sustainable development of coal chemical industry. The characteristics of ash have become the key factor to reflect the status and influence of the stable operation of coal gasification process. Introduce the current development and working principle of traditional characterization analysis of the composition,structure and morphology in gasification ash. Investigate the application of some new technologies,such as HTXRD,which can directly achieve the diffraction pattern of minerals at different temperature. Mssbauer spectroscopy can determine the iron materials in coal and ash through the qualitative and quantitative analysis,it also can test Fe2 +/ Fe3 +,crystal structure parameters,solid solution types and content. Microanalysis can test the micro-constitution of minerals using SEM and X-ray. The choice of analysis technologies should depend on the composition features of ash.

关键词(KeyWords)： 气化灰渣;灰渣矿物学;表征方法;高温X衍射;穆斯堡尔谱;微区分析
gasification ash;ash mineralogy;characterization methods;HTXRD;Mssbauer spectroscopy;microanalysis

Abstract:

Keywords:

基金项目(Foundation): 国家高技术研究发展计划(863计划)资助项目(2011AA050105)

作者(Authors): 邓云鹏;柳明月;袁小华;刘淑琴;
DENG Yunpeng;LIU Mingyue;YUAN Xiaohua;LIU Shuqin;School of Chemical and Environmental Engineering,China University of Mining and Technology (Beijing);

DOI: 10.13226/j.issn.1006-6772.2014.02.015

参考文献(References)：

• [1]高聚忠.煤气化技术的应用与发展[J].洁净煤技术,2013,19(1):65-71.
• [2]王玉倩.大型煤气化技术发展现状[J].煤炭加工与综合利用,2013(4):58-64.
• [3]吴秀章.中国煤炭转化的发展与机遇[J].洁净煤技术,2008,14(1):5-8.
• [4]李文,白进.煤的灰化学[M].北京:科学出版社,2013:7-72.
• [5]谢克昌.煤的结构与反应性[M].北京:科学出版社,2002:289-332.
• [6]郭树才.煤化工工艺学[M].3版.北京:化学工业出版社,2012:137-238.
• [7]朱海,王海涛.煤质特性对燃煤电厂炉型选择的影响[J].洁净煤技术,2012,18(6):49-52.
• [8]包良满,张元勋,金婵,等.燃煤小锅炉燃烧产物的SR-XRF和XANES分析[J].核技术,2008,31(9):641-647.
• [9]刘新斌,申琴芳,尚青龙,等.X射线荧光光谱法测定炉渣中的主要成分[J].光谱实验室,2005,22(1):58-61.
• [10]宋义,郭芬,谷松海,等.X射线荧光光谱法同时测定煤灰中的12种成分[J].光谱学与光谱分析,2008,28(6):1430-1434.
• [11]Aineto M,Acosta A,Ma J R,et al.Thermal expansion of slag and fly ash from coal gasification in IGCC power plant[J].Fuel,2006,85(16):2352-2358.
• [12]Karr Clarence.Analytical Methods for Coal and Coal Products[M].New York:Academic Press,1978:278.
• [13]Starsinic M,Squires E,Davis A.Concerning the 1600 cm-1region in the IR spectrum of coal[J].Fuel,1983,62(6):742-744.
• [14]Chadwick B L,Ashman R A,Campisi A,et al.Development of techniques for monitoring gas-phase sodium species formed during coal combustion and gasification[J].International Journal of Coal Geology,1996,32(1/4):241-253.
• [15]Schwenker R F,Garn P D.Thermal analysis[C]//Proceedings of the 2nd international conference of thermal analysis.Worcester Mass:Academic Press,1969:1377-1386.
• [16]Hill R,Rathbone R,Hower J C.Investigation of fly ash carbon by thermal analysis and optical microscopy[J].Cement and Concrete Research,1998(28):1479-1488.
• [17]戴正华,方秋霞,刘晓静.FeC2O4·2HO磁铁矿样品FeC2O4的物相分析[J].陕西师范大学学报:自然科学版,1998,26(4):115-116.
• [18]杨南如,夏元复,陈刚,等.用穆斯堡尔谱效应研究粉煤灰中含铁相[J].燃料化学学报,1984(4):375-381.
• [19]Cranshaw T E,Dale B W,Longworth G O,et al.Mssbauer Spectroscopy and Its Applications[M].Cambridge:Cambridge University Press,1985:119.
• [20]Bandyopadhyay D.Study of kinetics of iron minerals in coal by57Fe Mssbauer and FT-IR spectroscopy during natural burning[J].Hyperfine Interactions,2005,163(1/4):167-176.
• [21]Montano P A.Application of Mssbauer Spectroscopy to coal characterization and utilization[C]//Stevens J G,Shenoy G K.Mssbauer Spectroscopy and Its Chemical Applications.Washington D C:Am Chem Soc,1981:135-175.
• [22]Gracia M,Marco J F,Gancedo J R.Uses and perspectives of Mssbauer spectroscopy studies of iron minerals in coal[J].Hyperfine Interactions,1999,122(1/2):97-114.
• [23]杨新萍.X射线衍射技术的发展和应用[J].山西师范大学学报:自然科学版,2007,21(1):72-76.
• [24]范雄.金属X射线学[M].北京:机械工业出版社,1998.
• [25]田志宏,张秀华,田志广.X射线衍射技术在材料分析中的应用[J].工程与试验,2009,49(3):40-42.
• [26]Wrad C R.Analysis and significance of mineral matter in coal seams[J].International Journal of Coal Geology,2002,50(1/4):135-168.
• [27]Vassilev S V,Tascon J M D.Methods for characterization of inorganic and mineral matter in coal[J].Energy Fuels,2003,17(2):271-281.
• [28]Song Wenjia,Tang Lihua,Zhu Xuedong,et al.Fusibility and flow properties of coal ash and slag[J].Fuel,2009,88(2):297-304.
• [29]van Dyk J C,Melzer S,Sobiecki A.Mineral matter transformation during Sasol-Lurgi fixed bed dry bottom gasification-utilization of HT-XRD and FactSage modeling[J].Minerals Engineering,2006,19(10):1126-1135.
• [30]Vassilev S V,Vassileva C G.Methods for characterization of composition of fly ashes from coal-fired power stations:A critical overview[J].Energy Fuels,2005,19(3):1084-1098.
• [31]朱琳.扫描电子显微镜及其在材料科学中的应用[J].吉林化工学院学报,2007,24(2):81-84,92.
• [32]Barbara G,Kutchko,Ann G Kim.Fly ash characterization by SEM-EDS[J].Fuel,2006,85(17/18):2537-2544.
• [33]Kong L,Bai J,Li W,et al.Effects of operation parameters on slag viscosity in continuous viscosity[C]//3rd International symposium of gasification and its application.Vancouver:[s.n.],2012.
• [34]Huggins F E.Overview of analytical methods for inorganic constituents in coal[J].International Journal of Coal Geology,2002,50(1/4):169-214.
• [35]Goldstein J.Scanning Electron Microscopy and X-ray Microanalysis[M].New York:Springer,2003.
• [36]Marcio A,Kronbauer,Maria Izquierdo,et al.Geochemistry of ultra-fine and nano-compounds in coal gasification ashes:A synoptic view[J].Science of the Total Environment,2013,456/457(7):95-103.

文章评论(Comment)：